Titel
Highly chemoselective homologative assembly of the α-substituted methylsulfinamide motif from <i>N</i>-sulfinylamines
Autor*in
Davide Castiglione
Department of Chemistry, University of Turin
... show all
Abstract
α-Substituted methylsulfinamide are prepared through the homologation of electrophilic N-sulfinylamines with Li-CHXY reagents. The transformation takes place under full chemocontrol and exhibits good flexibility for preparing both N-aryl and N-alkyl analogues. Various sensitive functionalities can be accommodated on the starting materials, thus documenting a wide reaction scope.
Stichwort
Materials ChemistryMetals and AlloysSurfaces, Coatings and FilmsGeneral ChemistryCeramics and CompositesElectronic, Optical and Magnetic MaterialsCatalysis
Objekt-Typ
Sprache
Englisch [eng]
Persistent identifier
phaidra.univie.ac.at/o:2036110
Erschienen in
Titel
Chemical Communications
Band
59
Ausgabe
74
ISSN
1359-7345
Erscheinungsdatum
2023
Seitenanfang
11065
Seitenende
11068
Publication
Royal Society of Chemistry (RSC)
Erscheinungsdatum
2023
Zugänglichkeit
Rechte
Universität Wien | Universitätsring 1 | 1010 Wien | T
+43-1-4277-0