Titel
Ion-Specific Interactions at a Mineral-Water Interface Revealed by Surface-Sensitive Spectroscopy under Flow Conditions
Autor*in
Patrick Ober
Department of Molecular Spectroscopy, Max Planck Institute for Polymer Research
Autor*in
Sophia H. Kolbinger
Department of Molecular Spectroscopy, Max Planck Institute for Polymer Research
... show all
Abstract
A solid surface in contact with an aqueous solution is typically charged. When put in contact with an aqueous electrolyte solution, the surface charge and composition are crucially affected by the composition of the aqueous phase due to ion-specific interactions between ions and the solid surface. In this study, we combine surface-sensitive vibrational sum frequency generation (v-SFG) spectroscopy and flow experiments to investigate ion-specific interactions at the fluorite-water interface. The flow-induced change in the concentration of dissolved ions at the surface shifts chemical equilibria and can therefore influence the surface potential, which we probe by the v-SFG intensity in the OH stretch region. By studying the v-SFG intensity and its flow-induced change for different salts, we identify charge screening and ion-specific effects, including surface adsorption.
Stichwort
Surfaces, Coatings and FilmsPhysical and Theoretical ChemistryGeneral EnergyElectronic, Optical and Magnetic Materials
Objekt-Typ
Sprache
Englisch [eng]
Persistent identifier
https://phaidra.univie.ac.at/o:2036355
Erschienen in
Titel
The Journal of Physical Chemistry C
Band
127
Ausgabe
27
ISSN
1932-7447
Erscheinungsdatum
2023
Seitenanfang
13005
Seitenende
13010
Verlag
American Chemical Society (ACS)
Erscheinungsdatum
2023
Zugänglichkeit
Rechteangabe
© 2023 The Authors

Herunterladen

Universität Wien | Universitätsring 1 | 1010 Wien | T +43-1-4277-0